Molecular Interactions of First and Second Tier Dendrimers, Anticancer Molecules, Analyzed with Densities and Viscosities of Their Aqueous Mixtures

Authors

  • Man Singh Chemistry Research Lab., Deshbandhu College, University of Delhi, New Delhi
  • Ajaya Bhattarai Department of Chemistry, Mahendra Morang Adarsh Multiple Campus, Tribhuvan University, Biratnagar
  • R. K. Kale School of Life Science, Jawaharlal University, New Delhi
  • Shalini Gutpa Chemistry Research Lab., Deshbandhu College, University of Delhi, New Delhi
  • Sujeet Kumar Chatterjee Department of Chemistry, Mahendra Morang Adarsh Multiple Campus, Tribhuvan University, Biratnagar
  • K. C. Gupta Department of Chemistry, BSA College, Mathura

DOI:

https://doi.org/10.3126/jncs.v27i1.6440

Keywords:

Activation energy, Intrinsic viscosity, Frequency factor, Dendrimer

Abstract

Densities and viscosities of Tridiethymalonatetriazine (2,4,6) (TDEMTA) 1st (G1) and Hexadiethylmalonatetriazine (2,4,6) (HDEMTA) 2nd (G2) tier dendrimers for 0.62 to 10 mg % aqueous solutions are reported at 298.15 K and 303.15 K temperatures. Their data were compared with those of Trichlorotriazine (TCT), Triacetotrizine (TAT) and Trihydroxytrizine (THT) used as markers in the study. The densities for G2 are higher values than of G1 but both the dendrimers showed higher densities than those of the solvent with stronger heteromolecular forces due to stronger solvation and Intramolecular multiple force theory (IMMFT).

DOI: http://dx.doi.org/10.3126/jncs.v27i1.6440

J. Nepal Chem. Soc., Vol. 27, 2011 46-52

Uploaded date: 16 July, 2012

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Published

2012-07-16

How to Cite

Singh, M., Bhattarai, A., Kale, R. K., Gutpa, S., Chatterjee, S. K., & Gupta, K. C. (2012). Molecular Interactions of First and Second Tier Dendrimers, Anticancer Molecules, Analyzed with Densities and Viscosities of Their Aqueous Mixtures. Journal of Nepal Chemical Society, 27(1), 46–52. https://doi.org/10.3126/jncs.v27i1.6440

Issue

Vol. 27 (2011)

Section

Articles

License

© Journal of Nepal Chemical Society