Theoretical exploration of thermodynamic characteristics in lead-free liquid alloys: Zn-Bi-In System

Authors

  • Sanjay Kumar Sah Central Department of Physics, Tribhuvan University, Kirtipur, Kathmandu, Nepal
  • Indu Shekhar Jha Department of Physics, M.M.A.M. Campus, Tribhuvan University, Biratnagar, Nepal
  • Ishwar Koirala Central Department of Physics, Tribhuvan University, Kirtipur, Kathmandu, Nepal

DOI:

https://doi.org/10.3126/bibechana.v21i2.60097

Keywords:

Activity, Integral excess free energy, Solder alloys, Ternary liquid alloys, Molecular interaction volume model

Abstract

The calculations of Zn activities in the ternary liquid solder alloy Zn-Bi-In at 873 K were conducted through the application of the Molecular Interaction Volume Model (MIVM). The calculated values were compared to experimental data for three different cross-sectional examinations, namely for the bismuth-to-indium ratios (xBi: xIn) of 1:2, 1:1, and 2:1. Moreover, the integral excess free energy of these ternary liquid alloys was assessed using the same model parameters in order to test their validity. Then, the values were compared to the relevant experimental data reported in the literature that was already in existence. A satisfactory concordance has been observed between the theoretical predictions and the experimental findings.

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Published

2024-06-18

How to Cite

Sah, S. K., Jha, I. S., & Koirala, I. (2024). Theoretical exploration of thermodynamic characteristics in lead-free liquid alloys: Zn-Bi-In System. BIBECHANA, 21(2), 83–94. https://doi.org/10.3126/bibechana.v21i2.60097

Issue

Section

Research Articles